Are Styrofoam cups hot coffee safe?
Based on what we now know, you're probably safe using styrene foam cups for cold drinks, but I wouldn't use them for hot coffee or tea, and I would avoid using plastic containers for hot foods. You can recognize styrene foam cups at a glance.
If the cup is a polystyrene foam then no. The styrene monomers will break down, not only this but drinking out of foam cups can be toxic due to the chemicals Benzene and Styrene in the styrofoam. Do not drink tea with lemon, coffee with dairy cream, fruit juices, alcoholic beverages and wine.
In Styrofoam and PS cups studies, hot water was found to be contaminated with styrene and other aromatic compounds. It was observed that temperature played a major role in the leaching of styrene monomer from Styrofoam cups. Paper cups were found to be safe for hot drinks.
Styrofoam is an insulator, making it very poor at conducting heat. Heat can't pass on through to the water, so the Styrofoam disintegrates.
Studies show that styrene, a likely carcinogen, can leach from polystyrene foam cups and containers when heated. Never put hot food/drink into polystyrene foam containers, and never microwave these (or any plastic) products!
It leaches into food and drink.
and heat, a Styrofoam container's toxins (like benzene and styrene) seep into the contents. But even with cold or dry food, contact with Styrofoam is unhealthy. A huge portion of our food contains styrene contamination.
Styrofoam is made from expanded polystyrene, and it does not withstand heat well. It will start to soften at 212 °F, and it will melt at 464 °F. You can use styrofoam containers to preserve food in the fridge, but you can never reheat it or cook it in the oven.
Styrofoam insulates much more effectively than plastic, which means your cold drinks stay colder longer and your hot drinks stay hotter. Plastic cups are not recommended for hot drinks, and they do not have the insulation properties of Styrofoam.
2 These toxins can leach into food that is acidic, warm, alcoholic or oily and into the environment after exposure to rain and other weather. It is critical that people do not microwave food in Styrofoam or put hot food into Styrofoam containers.
Food-use Styrofoam containers, made from expanded polystyrene, are not oven safe. These Styrofoam containers will begin to soften at 212 degrees Fahrenheit and actually melt at 464 degrees. They are, however, safe to use for storing food in the refrigerator but never to cook or reheat in the oven.
Why is Styrofoam cup served with hot tea or coffee?
Styrofoam cup is used to serve hot tea or coffee because it is a bad conductor of heat. Or in other words, it is an insulator of heat. Styrofoam is made up of around 90% of air, and as we know that air is a bad conductor of heat, it makes styrofoam a good insulator.
Styrofoam drinking leach Styrofoam into the liquids they contain. The styrofoam containers apparently lose weight during the time they are in use. The migration of styrene from a polystyrene cup containing cold or hot beverages has been observed to be as high as 0.025% for a single-use.

Food-use Styrofoam containers are made from expanded polystyrene and are not oven safe to heat in a microwave. Styrofoam containers will begin to breakdown at 210 degrees Fahrenheit and melt at 460 degrees. This is hot enough to leach chemicals into your food and drink.
In the case of polystyrene, tiny amounts of styrene may remain following manufacture and it's this substance that may migrate. In 2014, the National Research Council in the US reviewed the evidence and concluded that styrene is “reasonably anticipated to be a human carcinogen”. However there is more to consider.
Most pieces of styrofoam accidentally swallowed are small enough that it is expected to pass through the GI tract without causing problems. When exposed to heat or acids, styrofoam breaks down, releasing toxic chemicals. This is why it is not considered microwave safe.
Polystyrene is toxic to human health.
Traditional Styrofoam
During normal use, the material remains stable. But at high temperatures, it begins to melt or break down. Even if there's no visible damage on the foam, a microwave oven may cause the toxic chemical styrene (among other chemicals) to leach into your food.
It's a technique designed to insulate the drink and protect the drinker from cold and condensation, and it's come to be known as the “Double Cup.” According to legend, it first became popular after an apparent landfill enthusiast in Rhode Island dreamed it up.
Styrofoam cups are non-biodegradable. Throwing away this much single-use plastic is harmful for several reasons. First, Styrofoam cups are non-biodegradable. Instead of breaking down over time, Styrofoam cups break into tiny pieces and stay in the environment for hundreds of years.
Polystyrene cups can leach harmful chemicals, like benzene, especially when they're microwaved, and animals sometimes mistake them for food and consume them. Paper cups — including polyethylene-coated ones — aren't toxic, even when microwaved or eaten accidentally.
Should you reuse Styrofoam cups?
If you are going to reuse Styrofoam containers for food item. Please don't do that. Scientists and environmentalists warn that such reuse has dangers. This type of reusing can cause bacterial contamination.
Most hospitals use foam products because foam products minimize exposure to bacteria and other foodborne pathogens compared to reusables. Foam is recyclable while also providing many consumer benefits. Foam products are lightweight, sturdy, inexpensive, and insulated. Foam cups can be recycled.
Styrofoam is made from expanded polystyrene, and it does not withstand heat well. It will start to soften at 212 °F, and it will melt at 464 °F. You can use styrofoam containers to preserve food in the fridge, but you can never reheat it or cook it in the oven.
If the temperature of the material reaches 210 degrees Fahrenheit or more, the Styrofoam starts to melt and releases toxic chemicals that can leach into your food. This can be very harmful for your health. It doesn't matter how long you microwave the food for, it's all about heat.
Polystyrene is considered safe for food use when in a solid state. However, heating can cause chemicals to leach from the foam and into the food. Eating the contents of a melted foam container one time is unlikely to cause harm. However, repeated exposure, which can be cumulative, can be a health risk.